2.4) Unfiled Notes
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To create a file/note outside of the notebooks click on the Unfiled Notes button and an application launcher will be shown on which application to launch. This opens up the application.

This is also best suited for creating files/notes for certain applications as well such as Krita or LibreOffice for example, those programs do not directly support launching an application with the file name as a parameter if the file does not exist, which means the New Section button is not an option for those programs. But these files can be opened so Open Section still works normally.